专利号:US-5767211-A 优先权日:1996-05-02 标 题:Synthesis of multi-functional hyperbranched polymers by polymerization of di-or tri-vinyl monomers in the presence of a chain transfer catalyst 发明人:GUAN ZHIBIN 权利人:DU PONT 摘要:This invention concerns the synthesis of multi-functional hyperbranched polymers by free radical polymerization of di- or tri-vinyl monomers in the presence of a chain transfer catalyst and a non-peroxide free radical initiator. The low viscosity and high functionality of these polymers make them useful for automotive coatings and for photopolymerization applications.
专利号:US-8933181-B2 优先权日:2006-10-06 标题:Branched polymers and methods for their synthesis and use 发明人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA 权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP 摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.
专利号:US-2005019747-A1 优先权日:2002-08-07 标 题 :Nanoliter-scale synthesis of arrayed biomaterials and screening thereof 发明人:ANDERSON DANIEL G; LEVENBERG SHULAMIT; LANGER ROBERT S 摘要:A method of screening cell-polymer interactions. The method includes depositing monomers as a plurality of discrete elements on a substrate, causing the deposited monomers to polymerize, thereby creating an array of discrete polymer elements on the substrate, incubating the substrate in a cell-containing culture medium, and characterizing a predetermined cell behavior on each polymer element.
专利号:US-7728088-B2 优先权日:2002-08-06 标题 :Synthesis of statistical microgels by means of controlled radical polymerisation 发明人:DESTARAC MATHIAS; BAVOUZET BRUNO; TATON DANIEL 权利人:RHODIA OPERATIONS 摘要:The invention relates to a method of preparing statistical microgels. The inventive method comprises a step involving the radical polymerisation of a composition containing: at least one monoethylenically-unsaturated monomer, at least one multiethylenically-unsaturated monomer, a free radical source and a control agent. The invention also relates to first generation microgels thus prepared and all the compounds resulting from said microgels (next-generation microgels).
专利号:US-2025101240-A1 优先权日:2023-09-26 标题 :Method and system for synthesis of a three-dimensional (3d)-printable hydrophilic silicone based elastic composite material 发明人:TANG XIAOWU (SHIRLEY); GANGULY SAYAN; WONG LI YAN 权利人:TANG XIAOWU SHIRLEY; GANGULY SAYAN; WONG LI YAN 摘要:The disclosure is directed at a method of fabricating a hydrophilic silicone-based ink product for use in three-dimensional printing and the ink itself. The ink includes a hydrophilic silicone, at least one vinylic monomer, at least one multi-vinylic monomer and a water-based initiator.
专利号:US-7763357-B2 优先权日:2005-01-27 标 题:Polymer composite synthesis in supercritical fluids 发明人:CHARPENTIER PAUL A; LI XINSHENG 权利人:CHARPENTIER PAUL A; LI XINSHENG 摘要:A one step synthetic route of polymeric compositions of a polyolefin and inorganic network consisting of components selected from Si, Zr, Ti, is disclosed. The synthetic route combines parallel reactions of free radical polymerization to form polymer, and hydrolysis of either Si, or Zr, or Ti or both of them precursors. The network consisting of Si, Zr, Ti, is chemically bonded to or within the polymer matrix. The inorganic or organic molecules can then be polymerized under conditions effective to cause the polymerized inorganic or organic molecules into macromolecular networks. The compositions of the polymeric composites can be easily controlled by adjusting the reactant ratio and reaction rate or conditions such as temperature and pressure, wherein the inorganic compositions disperse in nanoscale within polymeric composites when their concentrations fall below moderate levels. A novel synthesis route for making polymer composites and/or polymer nanocomposites of a polyolefin and an inorganic network consisting of components selected from Si, Zr, Ti, is disclosed. The synthesis route comprises hydrolysis of either Si, or Zr, or Ti alkoxides or mixtures of these precursors within a polymer matrix in supercritical fluids.
1: Bielecka-Kowalska A, Czarny P, Wigner P, Synowiec E, Kowalski B, Szwed M, Krupa R, Toma M, Drzewiecka M, Majsterek I, Szemraj J, Sliwinski T, Kowalski M. Ethylene glycol dimethacrylate and diethylene glycol dimethacrylate exhibits cytotoxic and genotoxic effect on human gingival fibroblasts via induction of reactive oxygen species. Toxicol In Vitro. 2018 Mar;47:8-17. doi: 10.1016/j.tiv.2017.10.028. Epub 2017 Oct 28. 27(18):5970. doi: 10.3390/molecules27185970.
合成参考文献
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