CAS: 2358-84-1; Oxybis(Ethane-2,1-Diyl) Bis(2-Methylacrylate)

该化合物是一种无色,粘液液体,在各种聚合工艺中可用作多功能单体,其特点是两种甲基丙烯酸性功能组,可以交叉连接聚合物网络,提高由此产生的材料的机械特性和热稳定性.DEGDMA在丙酮和乙醇等有机溶剂中可溶解,但在水中溶解性有限.它通常用于生产牙科材料,涂层,粘合剂和作为紫外线固化剂的组成部分.该物质具有低挥发性,而且具有相对较高的沸点,适合需要耐久性的应用.然而,必须小心地处理DEGDMA,因为它在接触时可引起皮肤和眼部的刺激.此外,应当采取适当的安全措施,以避免吸入或摄入,因为它可能具有毒理学影响.总的来说,DEGDMA在化工业中受到重视,因为它能够提高各种聚合系统性能.

结构式图片

相似化合物

109-16-0 109-17-1 97-90-5

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

上下游产品

CAS号131326-39-1 2-(2-((叔丁基二甲基硅烷... | CAS号920-46-7 甲基丙烯酰氯 | CAS号111-46-6 二乙二醇 | CAS号868-77-9 甲基丙烯酸羟乙酯 | CAS号77-73-6 二聚环戊二烯 | CAS号80-62-6 甲基丙烯酸甲酯 | CAS号79-41-4 甲基丙烯酸

合成工艺路线路线简述

  • 112-35-6 = 2358-84-1 + 109-16-0 + 868-77-9 + 2351-42-0 + 2351-43-1 + 24493-59-2 + 45103-58-0 + 6976-93-8 + 97-90-5 + 629-38-9
    反应条件:1.1 Catalysts: Phenothiazine,P-Toluenesulfonic Acid Solvents: Toluene; 4 H,120 °C
    标题:Side Products Of Methacrylic Acid Esterification With Triethylene Glycol Methyl Ether
    作者:Demidova,Yu. V.; Demidov,P. A.; Potekhin,V. V.; Potekhin,V. M.
    参考文献:Russian Journal Of General Chemistry 日期:2016 卷标:86(6) 页码:1250-1254
甲基丙烯酸甲酯,二乙二醇置于calcium Glycerate,4-甲氧基苯酚体系中,用89.3%的收率获得二乙二醇二甲基丙烯酸酯
参考文献:一种甘油钙催化合成二甘醇二(甲基)丙烯酸酯的方法
标题:一种甘油钙催化合成二甘醇二(甲基)丙烯酸酯的方法
摘要:本发明公开了一种甘油钙催化合成二甘醇二(甲基)丙烯酸酯的方法,属于精细化工领域.以(甲基)丙烯酸烷基酯,二甘醇为原料,采用反应‑精馏耦合工艺,使用铜丝网填料的改装精馏柱,加入催化剂甘油钙,经过简单后处理过程,能够获得足够的产物纯度及收率.本发明克服了现有酯交换催化剂的诸多不足,收率高,后处理简单.与传统酯交换法比较,本发明方法可提高总收率和处理能力,利用反应热供分离所需能量,降低能耗,减少投资.本发明方法工艺流程简短,原料易得,设备简单,反应条件易于控制.本方法反应条件温和,纯化精制工艺简单,产品稳定易分离,不易发生聚合现象.

海关参考信息

专利信息


专利号:US-5767211-A
优先权日:1996-05-02
标 题:Synthesis of multi-functional hyperbranched polymers by polymerization of di-or tri-vinyl monomers in the presence of a chain transfer catalyst
发明人:GUAN ZHIBIN
权利人:DU PONT
摘要:This invention concerns the synthesis of multi-functional hyperbranched polymers by free radical polymerization of di- or tri-vinyl monomers in the presence of a chain transfer catalyst and a non-peroxide free radical initiator. The low viscosity and high functionality of these polymers make them useful for automotive coatings and for photopolymerization applications.

专利号:US-8933181-B2
优先权日:2006-10-06
标题:Branched polymers and methods for their synthesis and use
发明人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA
权利人:MOURI HIROSHI; LUO STEVEN; KURASCH JESSICA; ROBERTSON CHRISTOPHER G; WARREN SANDRA; BRIDGESTONE CORP
摘要:Branched polymers including multi-branched polymers, functionalized branched polymers, star-branched polymers, and dendigraft polymers. Methods for the synthesis of branched polymers and method for the use of branched polymers in tire components are also included.

专利号:US-2005019747-A1
优先权日:2002-08-07
标 题 :Nanoliter-scale synthesis of arrayed biomaterials and screening thereof
发明人:ANDERSON DANIEL G; LEVENBERG SHULAMIT; LANGER ROBERT S
摘要:A method of screening cell-polymer interactions. The method includes depositing monomers as a plurality of discrete elements on a substrate, causing the deposited monomers to polymerize, thereby creating an array of discrete polymer elements on the substrate, incubating the substrate in a cell-containing culture medium, and characterizing a predetermined cell behavior on each polymer element.

专利号:US-7728088-B2
优先权日:2002-08-06
标题 :Synthesis of statistical microgels by means of controlled radical polymerisation
发明人:DESTARAC MATHIAS; BAVOUZET BRUNO; TATON DANIEL
权利人:RHODIA OPERATIONS
摘要:The invention relates to a method of preparing statistical microgels. The inventive method comprises a step involving the radical polymerisation of a composition containing: at least one monoethylenically-unsaturated monomer, at least one multiethylenically-unsaturated monomer, a free radical source and a control agent. The invention also relates to first generation microgels thus prepared and all the compounds resulting from said microgels (next-generation microgels).

专利号:US-2025101240-A1
优先权日:2023-09-26
标题 :Method and system for synthesis of a three-dimensional (3d)-printable hydrophilic silicone based elastic composite material
发明人:TANG XIAOWU (SHIRLEY); GANGULY SAYAN; WONG LI YAN
权利人:TANG XIAOWU SHIRLEY; GANGULY SAYAN; WONG LI YAN
摘要:The disclosure is directed at a method of fabricating a hydrophilic silicone-based ink product for use in three-dimensional printing and the ink itself. The ink includes a hydrophilic silicone, at least one vinylic monomer, at least one multi-vinylic monomer and a water-based initiator.

专利号:US-7763357-B2
优先权日:2005-01-27
标 题:Polymer composite synthesis in supercritical fluids
发明人:CHARPENTIER PAUL A; LI XINSHENG
权利人:CHARPENTIER PAUL A; LI XINSHENG
摘要:A one step synthetic route of polymeric compositions of a polyolefin and inorganic network consisting of components selected from Si, Zr, Ti, is disclosed. The synthetic route combines parallel reactions of free radical polymerization to form polymer, and hydrolysis of either Si, or Zr, or Ti or both of them precursors. The network consisting of Si, Zr, Ti, is chemically bonded to or within the polymer matrix. The inorganic or organic molecules can then be polymerized under conditions effective to cause the polymerized inorganic or organic molecules into macromolecular networks. The compositions of the polymeric composites can be easily controlled by adjusting the reactant ratio and reaction rate or conditions such as temperature and pressure, wherein the inorganic compositions disperse in nanoscale within polymeric composites when their concentrations fall below moderate levels. A novel synthesis route for making polymer composites and/or polymer nanocomposites of a polyolefin and an inorganic network consisting of components selected from Si, Zr, Ti, is disclosed. The synthesis route comprises hydrolysis of either Si, or Zr, or Ti alkoxides or mixtures of these precursors within a polymer matrix in supercritical fluids.
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主要参考文献


1: Bielecka-Kowalska A, Czarny P, Wigner P, Synowiec E, Kowalski B, Szwed M, Krupa R, Toma M, Drzewiecka M, Majsterek I, Szemraj J, Sliwinski T, Kowalski M. Ethylene glycol dimethacrylate and diethylene glycol dimethacrylate exhibits cytotoxic and genotoxic effect on human gingival fibroblasts via induction of reactive oxygen species. Toxicol In Vitro. 2018 Mar;47:8-17. doi: 10.1016/j.tiv.2017.10.028. Epub 2017 Oct 28. 27(18):5970. doi: 10.3390/molecules27185970.

合成参考文献


摘要:Paffenbarger GC, Rupp NW; Kirk-Othmer Encycl Chem Technol. John Wiley & Sons: NY, NY 7: 505 (1979)
摘要:NIOSH; National Occupational Exposure Survey (NOES) (1983)
摘要:Franke C et al; Chemosphere 29: 1501-14 (1994)
摘要:Mill T et al; Environmental Fate and Exposure Studies Development of a PC-SAR for Hydrolysis: Esters, Alkyl Halides and Epoxides. EPA Contract No. 68-02-4254. Menlo Park, CA: SRI International (1987)
摘要:Compound: 2-Propenoic acid, 2-methyl-, 1,1′-(oxydi-2,1-ethanediyl) ester, homopolymer
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