专利号:US-5663365-A 优先权日:1996-10-29 标 题:Process for the preparation of pyrazolones 发明人:YAMAMOTO YASUO; SHIRAKAWA NAOKI; TAKANO SHINICHI; KAWAI YOSHIO 权利人:JAPAN HYDRAZINE CO LTD 摘要:A process for the preparation of pyrazolone derivatives represented by the general formula ##STR1## wherein R is a hydrogen atom, an alkyl group, an allyl group, an aryl group or an aralkyl group, and R 1 and R 2 are, respectively, a hydrogen atom, an alkyl group or a phenyl group which may have a substituent, comprising reacting a 2,3-dihalocarboxylic acid derivative or a 2-haloacrylic acid derivative with a hydrazine derivative. A pyrazolone or 1-substituted-3-pyrazolones useful as intermediate starting materials for the synthesis of agricultural chemicals, medicine and chemical compounds can be easily and cheaply prepared from widely used industrial starting materials.
专利号:US-6949676-B2 优先权日:2002-01-03 标 题:Alkyl esters of the 2-(2-fluorosulphonyl)-perfluoroethylenoxy-3-halogen-propionic acid 发明人:TORTELLI VITO; MACULAN SARA 权利人:AUSIMONT SPA 摘要:Compounds of formula CH 2 Y—CH(COOR 1 )—O—CF 2 CF 2 —SO 2 F, usable in the synthesis of the fluorosulphonic vinylether —CF 2 â•?CF—O—CF 2 CF 2 —SO 2 F.
参考标题:Preparation Of α-Haloacrylate Derivatives Via Dimethyl Sulfoxide-Mediated Selective Dehydrohalogenation 作者:Wei Li,Jianchang Li,Zhao-Kui Wan,Junjun Wu,Walter Massefski |发布日期:2007.10.1 摘要:Selective Dehydrohalogenation To Form Alpha-Haloacrylate Analogues. A Variety Of Alpha-Halo Michael Acceptors Were Prepared In Dimethyl Sulfoxide Under Mild, Base-Free Conditions, Including The Preparation Of Alpha-Bromoacrolein And Alpha-Chloro- And Bromoacrylonitriles. Synthesis Of These Molecules Has Been Reported In The Literature To Be Difficult. Among All The Existing Dehydrohalogenation Procedures
合成参考文献
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