CAS: 103-38-8; Benzyl 3-Methylbutanoate

相似化合物

503-74-2 503-74-2 10361-39-4

上下游产品

CAS号108-64-5 3-甲基丁酸乙酯 | CAS号100-51-6 苯甲醇 | CAS号1262801-37-5 3-methyl-1-oxob... | CAS号1468-39-9 异戊酸酐 | CAS号1160845-88-4 benzyl 2-hydraz... | CAS号71338-71-1 (E)-丁基-2-烯酸苄酯 | CAS号1262801-36-4 3-methyl-1-oxob... | CAS号352-66-9 3-methylbutyroy... | CAS号503-74-2 异戊酸

C12H16N2O2置于1,8-二氮杂双环[5.4.0]十一碳-7-烯体系中,用 氯仿 用作溶剂,化学反应 24.0H,以80%的收率获得3-甲基丁酸苯甲酯
参考文献:有效的三步法进行α-氨基酯的脱氨基反应.在合成cyslt1拮抗剂中的应用
标题:有效的三步法进行α-氨基酯的脱氨基反应.在合成cyslt1拮抗剂中的应用
摘要:报道了一种用于α-氨基酯的脱氨的实用且有效的三步顺序.该方法基于nabh 4介导的将α-重氮酸酯选择性还原为α-肼基酸酯的方法,已成功应用于多种代表性的α-氨基酯的脱氨反应,包括一些1-半胱氨酸乙酯衍生物,这是合成α-半胱氨酸的关键中间体. Cyslt1拮抗剂系列.
Doi:10.1016/j.Tetlet.2009.03.118

专利信息

专利号:US-4523022-A
优先权日:1983-07-07
标 题:Analogs of the antibiotic spectinomycin
发明人：THOMAS RICHARD C
权利人:UPJOHN CO
摘要:The present invention concerns the novel, sugar-ring expansion for synthesis of novel analogs of spectinomycin or C-6' analogs of spectinomycin from known aminomethyldihydrospectinomycin and analogs thereof. Additionally, the invention concerns the novel synthesis of novel 7 membered sugar-ring analogs of dihydrospectinomycin and C-6' analogs thereof from novel 7 membered sugar-ring spectinomycin and C-6' analogs thereof by treatment with NaBH4.

专利号:US-11040939-B1
优先权日:2020-06-23
标 题 :N-transfer reagent and method for preparing the same and its application
发明人：CHOU HO-HSUAN; LU GUAN-HAN; HSUEH HSIAO-CHIN; HUANG TZU-CHIA
权利人:UNIV NAT CHENG KUNG
摘要:Provided are a novel N-transfer reagent and a method for preparing the same and its application. The N-transfer reagent is represented by the following Formula (I): n n n n n n n n n n The various novel N-transfer reagents of the present invention can be quickly prepared by employing different nitrobenzene precursors. The N-transfer reagents can directly convert a variety of amino compounds into diazo compounds under mild conditions. Particularly, the N-transfer reagents can facilitate the synthesis of the diazo compounds. The application of synthesizing diazo compounds of the present invention can greatly decrease the difficulty in operation, increase the safety during experiments, reduce the cost of production and the environmental pollution, and enhance the industrial value of diazo compounds.

专利号:US-4107183-A
优先权日:1975-12-08
标 题:Synthesis of optically active carboxylic acid esters

专利号:US-7301045-B2
优先权日:2000-10-16
标 题 :Method for preparing ester condensate
发明人：ISHIHARA KAZUAKI; YAMAMOTO HISASHI
权利人:JAPAN SCIENCE & TECH CORP
摘要:The present invention provides a method for preparing ester or thioester that can conduct catalytic esterification reaction with an equimolar amount of carboxylic acid and alcohol, or catalytic thioesterification reaction with carboxylic acid and an equimolar amount or small amount of thiol, and can be expected as an industrial method that needs an enormous amount of synthesis in the light of green chemistry. By using hafnium chloride (IV), especially tetravalent hafnium compounds represented by hafnium chloride (IV)·(THF) 2 or hafnium (IV)t-butoxide as a (poly) condensation catalyst, direct condensation reaction is conducted from carboxylic acid and an equimolar amount of alcohol or a little smaller amount of thiol, in the nonpolar solvent such as toluene and the like, in a deoxidization atmosphere and under heating reflux, and the reaction synthesizes ester monomer or thioester monomer, polyester or polythioester. When heating reflux is conducted by using a nonpolar solvent, it is preferable to remove azeotropic water from the reaction system.