专利号:US-3972951-A 优先权日:1966-12-14 标题:Process for the formation of 2,6-diphenyl-phenol 发明人:KAPNER ROBERT S; KIPPAX DONALD L; MURPHY KEVIN E; UDANI LALITKUMAR H 权利人:GEN ELECTRIC 摘要:A process for the formation of 2,6-diphenylphenol involving the autocondensation of cyclohexanone with itself to form a mixture of cyclic ketones containing a tricyclic ketone fraction and the dehydrogenation of the tricyclic ketone fraction to form 2,6-diphenylphenol. The process is characterized by reaction conditions permitting the formation of 2,6-diphenylphenol on a commercial scale that is free of impurities and suitable for many new applications requiring high purity as synthesis of drugs, plastics and the like.
专利号:EP-4286045-A1 优先权日:2022-06-03 标题:Synthesis of polymer adsorbent for passive air sampling 发明人:ERDOGAN BEDRI TUBA; SARIOGLAN SERIFE; ÜNVEREN ELIF; BAYIR SÜMEYRA; CEYLAN ÖZCAN 权利人:TUBITAK 摘要:The present invention provides new properties by adding boron nitride nanosheet (BNNS) (13) as well as chemically synthesizing the VOC adsorbent. Poly(2,6-diphenyl-p-phenylene oxide) (PPPO), known under the trademark of Tenax, was produced as a polymeric adsorbent by reinforcing with BNNS in granule form and high capacity, and it was called as MPPPO-BN adsorbent (21). The use of MPPPO-BN adsorbent (21) as an adsorbent material for VOCs has been proven by desorption tests from ambient temperature to 340°C depending on VOCs.The product developed with BNNS additive, being used as a polymeric adsorbent, has the capacity to adsorb more VOCs, prevent the agglomeration of polymer particles, and have a higher density than Tenax TA and Tenax GR.
专利号:US-3979460-A 优先权日:1974-07-01 标 题 :Process for the preparation of an organomercaptophenol from sulfur, a 2,6-disubstituted phenol, and an activated olefin or an epoxy compound 发明人:HAY ALLAN S 权利人:GEN ELECTRIC 摘要:A process for the preparation of an organomercaptophenol is described which comprises the reaction of sulfur with a 2,6-disubstituted phenol carried out in the presence of (1) a base, (2) an activated olefin or an epoxy compound, (3) and a solvent with a high dielectric constant. The organomercaptophenols produced by this process are useful as monomers in the synthesis of esters, carbonates, ethers, epoxy compounds, among many other chemicals synthesized from monohydric phenols. In addition, the oganomercaptophenols are also useful as antioxidants.
专利号:US-4064158-A 优先权日:1974-07-01 标题:Process for the preparation of an organomercaptophenol from sulfur, a 2,6-disubstituted phenol, and an activated olefin or an epoxy compound 发明人:HAY ALLAN S 权利人:GEN ELECTRIC 摘要:A process for the preparation of an organomercaptophenol is described which comprises the reaction of sulfur with a 2,6-disubstituted phenol carried out in the presence of (1) a base, (2) an activated olefin or an epoxy compound, (3) and a solvent with a high dielectric constant. The organomercaptophenols produced by this process are useful as monomers in the synthesis of esters, carbonates, ethers, epoxy compounds, among many other chemicals synthesized from monohydric phenols. In addition, the organomercaptophenols are also useful as antioxidants.
专利号:US-11155505-B2 优先权日:2017-02-17 标题 :Synthesis of pheromones and related materials via olefin metathesis 发明人:WAMPLER KEITH M; BUI VU; ROZZELL DAVID; COELHO PEDRO; FLORUTI ARTHUR; ONDI LEVENTE; MEHDI HASAN; EROS GABOR 权利人:PROVIVI INC 摘要:Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.
专利号:US-5596115-A 优先权日:1994-11-04 标题:Compounds of rhenium and aluminium, preparation thereof and use thereof as catalysts 发明人:COMMEREUC DOMINIQUE 权利人:INST FRANCAIS DU PETROLE 摘要:The present invention concerns new compounds of rhenium and aluminum corresponding to the general formula: O 3 Re--O--[Al(OR)(L) x --O] n --ReO 3 in which R is a hydrocarbyl residue, for example alkyl, cycloalkyl, alkenyl, aryl and aryl or cycloalkyl which are substituted, containing from 1 to 40 carbon atoms, which residue can be substituted by alkoxy groups or by halogens, L is the synthesis solvent, x is equal to 0 or 1 and n is an integer of from 1 to 10. The invention also concerns derived compounds of the formula O 3 Re(L')--O--[Al(OR)(L) x --O] n --ReO 3 (L') in which L' is a stabilising ligand. The invention also concerns the preparation of such compounds and the use thereof in the preparation of catalysts.