CAS: 7783-56-4; Antimony Trifluoride

该化合物是一种无机化合物,其特点是室内温度为白色晶状固体形式,以高反应力而闻名,特别是刘易斯酸,它能形成各种子体的复合体.三氟化氮具有分子结构,将微粒原子捆绑在三个氟原子中,从而形成三角金字塔式的几何.这种化合物在极地溶解,可以作为有机合成中的氟化剂.它还被用于生产其他反蚁化合物和各种工业应用中.三氟化氮被视为有毒,在接触时会构成健康风险,在处理过程中需要采取适当安全措施.其化学特性包括能够在水中进行水解,从而形成反氧化物氧化物和氟酸.

结构式图片

欧盟法规

统一分类与标签压力设备指令-第1组危险流体REACH注册ECHA物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

上下游产品

CAS号10025-91-9 三氯化锑 | CAS号7440-36-0 锑粒 | CAS号7783-70-2 五氟化锑 | CAS号432-05-3 tris(trifluorom... | CAS号7789-33-5 一溴化碘 | CAS号7664-39-3 氟化氢 | CAS号7783-54-2 三氟化氮 | CAS号7791-16-4 antimony dichlo... | CAS号7783-81-5 六氟化铀 | CAS号6141-72-6 N-[bis(trifluor... | CAS号105396-09-6 ditert-butyl(fl... | CAS号373-74-0 甲基三氟硅烷 | CAS号420-58-6 Dichlorofluoro(... | CAS号430-88-6 erythreo-1-brom... | CAS号471-43-2 1,1-二氯-2,2-二氟乙烷 | CAS号359-28-4 1-氟-1,2,2-三氯乙烷 | CAS号430-89-7 1-bromo-1-chlor... | CAS号358-60-1 一氟三乙氧基硅烷 | CAS号460-55-9 ethoxy(trifluor...

合成工艺路线路线简述

  • 合成目标产物 Antimony Trifluoride 主要起始原料 Antimony Trichloride
  • (文献来源)合成步骤主要原料 Antimony Trichloride
亚锑氢化物置于calcium Fluoride体系中,化学反应生成 三氟化锑
参考文献:Flueckiger,F. A.,Annalen Der Physik,1852,Vol. 87,P. 250
标题:Flueckiger,F. A.,Annalen Der Physik,1852,Vol. 87,P. 250

专利信息


专利号:US-2023286918-A1
优先权日:2020-07-02
标 题:Manufacturing process for 3,5-dichloropicolinonitrile for synthesis of vadadustat
发明人:JURKAUSKAS VALDAS; JUNG YOUNG CHUN; KWON TAESOO; KANNAN ARUNACHALAM; GONDI VIJAYA BHASKER
权利人:AKEBIA THERAPEUTICS INC
摘要:Disclosed herein are methods and processes of preparing vadadustat or a pharmaceutically acceptable salts thereof, and intermediates (e.g., a compound of Formula (I), (I-F), (II), or (IV), or a pharmaceutically acceptable salts thereof) useful for the synthesis of vadadustat.

专利号:US-5196600-A
优先权日:1992-03-25
标题 :Synthesis of fluorinated dimethyl ethers
发明人:O'NEILL GERALD J
权利人:GRACE W R & CO
摘要:A novel process is disclosed for the synthesis of fluorinated dimethyl ethers of the formula CF 2 HOCCl x F y H 3- (x+y) wherein x is 0, 1 or 2; y is 1, 2 or 3; and wherein the total x+y is 1, 2 or 3. The process involves chlorination of methyl difluoromethyl ether to form a chlorinated reaction product, including at least one compound of the formula CF 2 HOCH 3-z Cl z , wherein z is 1, 2 or 3, which compound is then fluorinated with HF and/or an antimony salt and with or without separation from the chlorinated reaction product, to give a fluorinated reaction product including the aforementioned fluorinated dimethyl ethers.

专利号:US-5185474-A
优先权日:1990-10-02
标 题:Synthesis of fluorinated dimethyl ethers
发明人:O'NEILL GERALD J
权利人:GRACE W R & CO
摘要:A novel process is disclosed for the synthesis of fluorinated dimethyl ethers of the formula CF 2 HOCCl X F Y H 3- (X+Y) wherein X and Y are each independently 0, 1, 2 or 3 and wherein the total X+Y is 2 or 3. The process involves chlorination of methyl difluoromethyl ether to form a chlorinated reaction product, including at least one compound of the formula CF 2 HOCH 3-z Cl z , wherein z is 1, 2 or 3, which compound is then fluorinated, with or without separation from the chlorinated reaction product, to give a fluorinated reaction product including the aforementioned fluorinated dimethyl ethers.

专利号:US-4756739-A
优先权日:1985-12-21
标题 :Pyridine derivatives and the N-oxides thereof, and the use thereof as intermediates for the synthesis of plant protecting agents
发明人:FUSS ANDREAS; KOCH VOLKER
权利人:HOECHST AG
摘要:The compounds of the formula I (I) in which A denotes N or N->O, Z denotes O or NH, R denotes H, (halo)alkyl, (halo)alkenyl, (halo)alkynyl or alkoxycarbonyl, R1 denotes hydrogen, halogen, amino, -NHOH, hydroxyl, (substituted) phenylazo or a radical of the formulae Y=C=N-, Y1Y2C=N-, Y3NH- or K denotes 0 or 1, and m and n, independently of one another, denote a number from 1 to 4, with the proviso that, when Z-R denotes OH or NH2, (R1)n denotes at least one radical of the formula or represents two radicals, in the 5 or 6 position of the heterocyclic ring, which, in the 5 position, denote halogen and, in the 6 position, denote a radical of the group comprising halogen, amino, hydroxyl or phenylazo, which may be substituted as specified above, are valuable intermediates in the synthesis of plant protection agents.

专利号:US-2024368075-A1
优先权日:2021-07-02
标题 :Synthesis of N,N-Dialkyl, -Dialkenyl, -Dialkynyl, and Related Cyclics, Sulfamoyl Fluoride Compounds Using Hydrogen Fluoride
发明人:SINGH RAJENDRA P; HU QICHAO
权利人:SES HOLDINGS PTE LTD
摘要:Methods of producing N,N-dimethyl sulfamoyl fluoride and related derivatives of the formula F—S(O)2—NR2 (I) by contacting a sulfamoyl nonfluorohalide compound of the formula X—S(O)2—NR2 (II) with anhydrous hydrogen fluoride under conditions sufficient to produce the N,N-dimethyl sulfamoyl fluoride or derivative thereof of Formula I, wherein R in each of Formulas I and II is, independently, a linear or branched alkyl, alkenyl, or alkynyl group containing 1 to 12 carbon atoms, the Rs can be joined to form a cyclic amine with the N, and X is any one of chlorine, bromine, and iodine.

专利号:US-2023322661-A1
优先权日:2020-08-21
标题 :Synthesis of N,N-Branched Sulfamoyl Fluoride Compounds Using Bismuth Trifluoride
发明人:SINGH RAJENDRA P; HU QICHAO; SHEIMAN JOHNATHAN
权利人:SES HOLDINGS PTE LTD
摘要:Methods of producing N,N-branched sulfamoyl fluoride compounds of the formula F-S(O) 2 -NR 2 by contacting bismuth trifluoride with an N,N-branched sulfamoyl nonfluorohalide compound of the formula X-SO 2 NR 2 , wherein X=chlorine (Cl), bromine (Br), or iodine (I), and each R is, independently, a linear or branched alkyl, fluoroalkyl, alkenyl, fluoroalkenyl, alkynyl, or fluoroalkynyl with 1 to 12 carbon atoms, to fluorinate the N,N-branched sulfamoyl nonfluorohalide compound. This is a non-aqueous method, the purity of product is very high, and the desired product can be isolated in quantitative yield. The N,N-branched sulfamoyl fluoride compounds so produced are useful in various applications including as electrolyte solvents and additives in electrochemical devices, such as lithium batteries and capacitors, and in biological fields, among others.
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合成参考文献


摘要:Aitken, R. A.; Boubalouta, Y., Science of Synthesis Knowledge Updates, (2013) 4, 145.
摘要:de Vries, J. G., Science of Synthesis: C-1 Building Blocks in Organic Synthesis, (2013) 1, 212.
摘要:Luckey, T.D. and B. Venugopal. Metal Toxicity in Mammals, 1. New York: Plenum Press, 1977., p. 179
摘要:Currance, P.L. Clements, B., Bronstein, A.C. (Eds).; Emergency Care For Hazardous Materials Exposure. 3rd revised edition, Elsevier Mosby, St. Louis, MO 2007, p. 462-3
摘要:40 CFR 401.15 (USEPA); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of March 2, 2018: https://www.ecfr.gov
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