CAS: 14098-24-9; Benzo-18-Crown 6-Ether

相似化合物

75460-28-5 68941-06-0 60835-75-8

上下游产品

o-hydroxyphenyl 3,6,9,12-tetraoxa-14-bromotetradecyl ether penta(ethylene glycol) bis(p-toluenesulfonate) benzene-1,2-diol pentaethylene glycol dimesylate2,3,6,7,10,11-hexamethoxytriphenylene 32H38O10C32H38O10 4'-nitrobenzo-18-crown-6 18-bromo-2,3,5,6,8,9,11,12,14,15-decahydrobenzo[b][1,4,7,10,13,16]Hexaoxacyclotetradecene

2-[2-(2-{2-[2-(2-Hydroxyethoxy)Ethoxy]Ethoxy}Phenoxy)Ethoxy]-1-Ethanol置于sodium Hydroxide,四丁基碘化铵,对甲苯磺酰氯体系中,用 甲苯 用作溶剂,化学反应 13.0H,以68%的收率获得苯并-18-冠-6-醚
参考文献:相转移催化条件下苯并冠醚的实用合成
标题:相转移催化条件下苯并冠醚的实用合成
摘要:苯并-12-皇冠-4,苯并-15-皇冠-5,苯并-18-皇冠-6,苯并-21-皇冠-7和苯并-24-皇冠-8的合成简便有效的程序已经开发了转移催化条件.
Doi:10.1055/s-2002-34853

专利信息

专利号:US-7091338-B2
优先权日:2001-11-15
标 题 :Purification of 4,4′(5′)- di-t-butylcyclohexano-18-crown-6
发明人：BOND ANDREW H; BARRANS JR RICHARD E; HORWITZ E PHILIP
权利人:PG RES FOUNDATION
摘要:A purification method is disclosed for a predetermined water-insoluble extractant present in a liquid phase composition that additionally contains one or more additional extractants, synthesis reaction starting materials, and reaction byproducts dissolved as solutes in an organic diluent. An ion-containing compound is admixed with the composition to form an extractant/ion complex in the organic diluent phase that has an affinity for a new phase that is greater than the affinity for the first-named phase. The predetermined extractant/ion complex is separated from the diluent by using the new phase affinity, and the extractant/ion complex is preferably although not necessarily recovered. The extractant/ion complex is separated into extractant and ion. The extractant is recovered. Exemplary extractants include polyethers, crown ethers, crown thioethers, calixarenes, polyamines, cryptands, porphyrins and the like.

专利号:CN-102875812-B
优先权日:2012-07-10
标题 :Synthesis of Cyclohexyl and Crown Ether Bonded Silicone Resin by Cocondensation Polymerization

专利号:CN-104262242-A
优先权日:2014-09-22
标 题:Synthesis of 3,5-diiodo-4-aminopyridine by in situ generation of iodo reagent

专利号:CN-102875812-A
优先权日:2012-07-10
标题:Synthesis of Cyclohexyl and Crown Ether Bonded Silicone Resin by Cocondensation Polymerization

专利号:US-6984734-B2
优先权日:2002-02-26
标 题 :Cyclo[n]pyrroles and methods thereto
发明人：SESSLER JONATHAN L; SEIDEL DANIEL; BOLZE FREDERIC R; KOEHLER THOMAS
权利人:UNIV TEXAS
摘要:The present invention provides an oxidative coupling procedure that allows efficient synthesis of novel cyclo[n]pyrrole macrocycles. Therefore, the present invention provides cyclo[n]pyrroles where n is 6, 7, 8, 9, 10, 11, or 12, and derivatives, multimers, isomers, and ion and neutral molecule complexes thereof as new compositions of matter. A protonated form of cyclo[n]pyrrole displays a gap of up to 700 nm between strong Soret and Q-like absorption bands in the electronic spectrum, demonstrating no significant ground state absorption in the visible portion of the electronic spectrum. Uses of cyclo[n]pyrroles as separation media, nonlinear optical materials, information storage media and infrared filters are provided.

专利号:CN-104003934-A
优先权日:2014-06-13
标题 :Synthesis of 6-chloro-3-fluoro-2-pyridinecarboxylic acid