CAS: 87-68-3; Hexachlorobutadiene

该化合物是合成有机化合物,其特点是氯化碳氢化合物结构;无色的黄液,其气味模糊,在水中不溶解,但在有机溶剂中可溶解;该化合物主要用作其他化学品生产的中间体,并在各种工业应用中用作溶剂;六氯丁二烯因其稳定性和耐降解性而闻名,因其持久性而可能造成环境问题;它被归类为一种危险物质,其潜在健康影响包括呼吸刺激和长期接触时可能致癌;在与该化合物合作时,适当的处理和安全措施对于减轻与其毒性和环境影响有关的风险至关重要;此外,管制框架可能规范其使用和处置,反映其对人类健康和环境的潜在风险.

结构式图片

欧盟法规

《欧盟PIC法规》欧盟《事先知情同意法规》附件五ECHA物质ECHA物质OtherC&L通报欧盟《水框架指令》附件XREACH预注册

上下游产品

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合成工艺路线路线简述

  • 合成目标产物 Hexachloro-1,3-Butadiene 主要起始原料 Tetrachloroethylene
  • (文献来源)合成步骤主要原料 Tetrachloroethylene
四氯乙烯置于zinc(II) Chloride体系中,化学反应 12.0H,反应生成 六氯-1,3-丁二烯
参考文献:一种六氯-1,3-丁二烯的制备方法
标题:一种六氯-1,3-丁二烯的制备方法
摘要:本发明提供一种六氯‑1,3‑丁二烯的制备方法,包括以下步骤:以三氯乙烯与四氯乙烯为原料,以无水金属氯化物为催化剂,金属氯化物可以为氯化铁,氯化铝,氯化锌中的一种或者多种,反应物为三氯乙烯,四氯乙烯中的一种或两种,三氯乙烯和四氯乙烯的摩尔比为0:100~100:0,催化剂质量分数为1%~20%.反应温度为50~250oc条件下,反应物的转化率在20%~80%,六氯‑1,3‑丁二烯的选择性在20%~60%.本方法工艺简单,操作简便,能耗低,原子利用率高.

海关参考信息

专利信息


专利号:US-7601774-B2
优先权日:2004-07-19
标题:Synthesis of aromatic polyhalogenated halomethyl compounds
发明人:KORNBERG NURIT; ADDA MICHAEL; PELED MICHAEL
权利人:BROMINE COMPOUNDS LTD
摘要:The present invention discloses a process for the preparation of highly pure pentabromobenzyl bromide, PBB-Br, wherein the benzylic bromination reaction is carried out in a suitable organic solvent in the presence of water and wherein the reaction temperature is such that it is sufficient to activate the initiator but not high enough to consume a substantial amount thereof.

专利号:US-7153921-B2
优先权日:2004-02-03
标 题 :Synthesis of elastomeric carborane-siloxanes by hydrosilation reactions
发明人:KELLER TEDDY M; KOLEL-VEETIL MANOJ K
权利人:US NAVY
摘要:A crosslinked polymer and process of making it are disclosed. A copolymer having at least one alkyne group, carborane group, and alkylsiloxane group is reacted with a siloxane crosslinker in a hydrosilation reaction. This produces a crosslinked polymer where the crosslink sites are reacted alkyne groups.

专利号:US-2005209355-A1
优先权日:2004-03-22
标 题:[Novel Reactions and the Products of Such Reactions]
发明人:ROITMAN LIPA L
权利人:ROITMAN LIPA L
摘要:A process for the synthesis of novel compounds is described comprising reacting tetrachloroethylene with substances containing active methylene group in the presence of free radical initiators. Also, a process for grafting tetrachloroethylene is described comprising reacting these compounds with polymers containing active methylene group in the presence of free radical initiators. Furthermore, a method of conducting such reactions to high conversion is described, comprising conducting the reactions in the reflux condensate. The present invention provides a novel and high yield route for heretofore unobtainable materials.

专利号:US-5098525-A
优先权日:1989-06-08
标 题 :Process for disposing of residues deriving from the synthesis of chlorinated hydrocarbons
发明人:LORENZONI LORENO; MESSINA GIUSEPPE; BRUZZI VITTORIO; SIMULA SALVATORE
权利人:ENICHEM ANIC SPA
摘要:The disposal of chlorinated pitches is carried out by a process which employs two treatments with an alcohol, which are carried out in cascade. n Such treatments cause the precipitation of the suspended matter to take place. This is then caused to settle, and is separated and pyrolized, while the supernatant is distilled in order to separate the alcohol, which is recycled back to the process, from other organic components, which are sent to further uses.

专利号:US-4246373-A
优先权日:1980-02-14
标 题 :Synthesis of substituted cyclopentadienes and cyclopentadiene-functionalized polymers
发明人:KENNEDY JOSEPH P; CASTNER KENNETH F
权利人:KENNEDY JOSEPH P; CASTNER KENNETH F
摘要:Aluminum cyclopentadienyl compounds can be used to synthesize a variety of organic molecules containing the cyclopentadiene group, e.g., substituted cyclopentadiene compounds, polymer molecules with cyclopentadiene pendant groups, and polymer molecules with cyclopentadiene terminal groups.

专利号:WO-2025019747-A1
优先权日:2023-07-20
标题:Processes for the production of z-1,1,1,4,4,4-hexafluoro-2-butene intermediates and compositions thereof
发明人:PENG SHENG
权利人:CHEMOURS CO FC LLC
摘要:Methods of synthesis of intermediates, such as 2-chloro-1,1,1,4,4,4-hexafluoro-2-butene and 2,3-dichloro-1,1,1,4,4,4-hexafluoro-2-butene, which can be used in the production fluorinated olefins, such as 1,1,1,4,4,4-hexafluoro-2-butene, from hexafluorobutadiene, are provided.
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合成参考文献


摘要:Beier, P., Science of Synthesis Knowledge Updates, (2014) 2, 315.
摘要:Toxicology and Applied Pharmacology., 48(A192), 1979
摘要:European Journal of Toxicology and Environmental Hygiene., 8(180), 1975
摘要:Gigiena i Sanitariya. For English translation, see HYSAAV., 37(2)(32), 1972
摘要:Chemistry of Pesticides, Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971, -(40), 1971
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