853-75-8 = 602-94-8 + 880-78-4 反应条件:1.1 Reagents: Trifluoroacetic Anhydride,Hydrogen Peroxide Solvents: Dichloromethane 标题:Fluoroaromatic Derivatives. Cii. Oxidation Of Fluorinated Benzylidene Anilines With Peracids 作者:Furin,G. G.; Et Al 参考文献:Journal Of Fluorine Chemistry 日期:1985 卷标:28(1) 页码:23-35]
= 602-94-8 + 880-78-4 反应条件:1.1 Reagents: Potassium Iodide Solvents: Chloroform2.1 Reagents: Trifluoroacetic Anhydride,Hydrogen Peroxide Solvents: Dichloromethane 标题:Fluoroaromatic Derivatives. Cii. Oxidation Of Fluorinated Benzylidene Anilines With Peracids 作者:Furin,G. G.; Et Al 参考文献:Journal Of Fluorine Chemistry 日期:1985 卷标:28(1) 页码:23-35
八氟甲苯置于硫酸体系中,化学反应生成 2,3,4,5,6-五氟苯甲酸 参考文献:A New General Route To Aromatic Fluorocarbons 标题:A New General Route To Aromatic Fluorocarbons 摘要: DOI:10.1038/183588A0
专利号:US-7956011-B2 优先权日:2005-05-04 标题:Materials and methods for the photodirected synthesis of oligonucleotide arrays 发明人:SERAFINOWSKI PAWEL JERZY; GARLAND PETER BRYAN 权利人:CANCER RES INST ROYAL 摘要:Materials and methods for photodirected synthesis of oligonucleotide arrays on a solid substrate by photodirected synthesis are disclosed which employ a film formed from (i) a photoacid generator that on photolysis generates acid that is capable of directly removing the protecting group of the linker molecules or oligonucleotides and (ii) a polymer substantially lacking electronegative heteroatoms that are capable of hydrogen bonding with photogenerated acid. Methods of synthesizing an oligomer arrays are also described that use a film that restricts diffusion of reactants and products on the substrate during synthesis of the array and which includes a precursor of a deprotecting reagent. The method involves removing one or more of the non-required products of the deprotection reaction from the reactive array elements at which they are produced during the reaction, in order to displace the deprotection reaction towards completion.
专利号:US-6770436-B1 优先权日:1996-11-14 标题:Chemical amplification for the synthesis of patterned arrays 发明人:BEECHER JODY E; GOLDBERG MARTIN J; MCGALL GLENN H 权利人:AFFYMETRIX INC 摘要:Radiation-activated catalysts (RACs), autocatalytic reactions, and protective groups are employed to achieve a highly sensitive, high resolution, radiation directed combinatorial synthesis of pattern arrays of diverse polymers. When irradiated, RACs produce catalysts that can react with enhancers, such as those involved in autocatalytic reactions. The autocatalytic reactions produce at least one product that removes protecting groups from synthesis intermediates. This invention has a wide variety of applications and is particularly useful for the solid phase combinatorial synthesis of polymers.
专利号:US-10676423-B2 优先权日:2017-02-21 标题 :Structure and synthesis of highly fluorinated amino acid derivatives 发明人:WEAVER JIMMIE DEAN; TEEGARDIN KIP ALLEN; ARORA AMANDEEP 权利人:UNIV OKLAHOMA STATE 摘要:Methods of synthesizing polyfluorinated amino acid derivatives are disclosed, along with polyfluorinated amino acid derivatives produced from said methods, as well as compositions containing same. The synthesis methods utilize an oxazolone and a perfluoroarene to produce the polyfluorinated amino acid derivatives.
专利号:US-6180830-B1 优先权日:1995-11-08 标题 :Method for preparing a bimetallic ruthenium/tin catalyst and a process for the synthesis of aldehydes 发明人:JACQUOT ROLAND 权利人:RHODIA CHIMIE SA 摘要:The present invention relates to a new process for the preparation of a bimetallic ruthenium/tin catalyst. The process for the preparation of a bimetallic ruthenium/tin catalyst according to the invention is characterised by the fact that it consists in carrying out the reduction of a ruthenium complex having an electrovalency of -4 and a coordination number of 6, the ligands being either a halogen atom or an anion or a tin halide. The catalyst is further employed for the preparation of aldehydes by reduction, in the vapor phase, of carboxylic acids, esters and anhydrides.
专利号:US-6229055-B1 优先权日:1996-04-12 标题 :Synthesis of fluorinated xanthene derivatives 发明人:KLAUBERT DIETER H; GEE KYLE R 权利人:MOLECULAR PROBES INC 摘要:Facile syntheses for fluorinated resorcinol and aminophenol derivatives are provided that yield isomer-free products in good yield. These novel methods use generally available precursors and standard laboratory reagents and equipment to reproducibly produce these synthetically useful reagents in relatively large quantities. The resulting fluorinated resorcinols and aniinophenols possess utility in the preparation of fluorinated fluorescein and rhodol dyes.
专利号:US-5214218-A 优先权日:1992-05-04 标题 :One step synthesis of methyl t-butyl ether from t-butanol using haloacid-modified clay catalysts 发明人:KNIFTON JOHN F 权利人:TEXACO CHEMICAL 摘要:A method is disclosed wherein t-butanol is reacted with methanol in a reaction zone in one step to provide methyl tert-butyl ether and the improvement of accomplishing the reaction which comprises: n a. Using a catalyst comprising a montmorillonite clay treated with a haloacid; n b. continuously contacting said t-butanol and methanol in a molar amount of about 0.1 to 10 moles of methanol per mole of t-butanol with said catalyst at a temperature of about 20° C. to about 250° C. and a pressure of about atmospheric to about 1000 psig to obtain the methyl tert-butyl ether product.
[参考文献]: H J Leis, Et Al. Quantitative Measurement Of Amphetamine In Human Plasma By Gas Chromatography/negative Ion Chemical Ionization Mass Spectrometry Using (2H5)Amphetamine As Internal Standard. Biol Mass Spectrom. 1994 Oct;23(10):637-41. [参考文献]: L Ravichandran, Et Al. Photovalorisation Of Pentafluorobenzoic Acid With Platinum Doped Tio2. J Hazard Mater. 2009 Aug 15;167(1-3):763-9. [参考文献]: L W Herman, Et Al. The Use Of Pentafluorophenyl Derivatives For The 18F Labelling Of Proteins. Nucl Med Biol. 1994 Oct;21(7):1005-10. [参考文献]: M Palit, Et Al. Determination Of Pentafluorobenzyl Derivatives Of Phosphonic And Phosphonothioic Acids By Gas Chromatography-Mass Spectrometry. J Chromatogr A. 2004 Jul 23;1043(2):275-84. [参考文献]: Nathan W Haws, Et Al. Dual-Domain Solute Transfer And Transport Processes: Evaluation In Batch And Transport Experiments. J Contam Hydrol. 2004 Dec;75(3-4):257-80.
合成参考文献
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