专利号:US-11926589-B2 优先权日:2019-07-09 标 题 :Process for the synthesis of non-racemic cyclohexenes 发明人:REISMAN SARAH; ROMBOLA MICHAEL; LADD CAROLYN L; MCLAUGHLIN MARTIN JOHN; ZUEND STEPHAN; GOETZ ROLAND 权利人:BASF CORP; CALIFORNIA INST OF TECHN 摘要:This invention relates to a process for the synthesis of a non-racemic cyclohexene compound of formula (I) by a Diels-Alder reaction of a compound of formula (II) with a compound of formula (III) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 and Y have the meanings as defined in the description in the presence of a catalyst comprising at least one m-valent metal cation M m+ wherein the metal M is selected from Scandium (Sc), Yttrium (Y), Lanthanum (La), Cerium (Ce), Praseodymium (Pr), Neodymium (Nd), Promethium (Pm), Samarium (Sm), Europium (Eu), Gadolinium 15 (Gd), Terbium (Tb), Dysprosium (Dy), Holmium (Ho), Erbium (Er), Thulium (Tm), Ytterbium (Yb), Lutetium (Lu), Gallium (Ga) and Indium (In), and m is an integer of 1, 2 or 3, and a chiral ligand of the formula (IV) wherein R 10a , R 10b , R 10c , R 10d , R 10a′ , R 10b′ , R 10c′ , R 10d′ , Z and Z′ have the meanings as defined in the description.
专利号:US-2024075466-A1 优先权日:2021-04-09 标 题:One-Pot Synthesis of Transition Metal-Promoted Chabazites 发明人:VAN TENDELOO LEEN; SCHUETZE FRANK-WALTER; VERHEYEN ELKE JANE JUNE 权利人:UMICORE AG & CO KG 摘要:The invention provides methods for a one-pot synthesis of molecular sieves of the CHA-type. The method uses molecular and non-molecular sieves as sources of silicon and aluminum. A first OSDA is selected from tetraethylenepentamine (TEPA) and triethy-lenepentamine (TETA). The synthesis mixture comprises a first metal selected from copper, iron and zinc. Optionally, the synthesis mixture may furthermore comprise a second OSDA and/or a second metal selected from manganese, cesium, magnesium, calcium, strontium, barium, yttrium, titanium, zirconium, niobium, iron, zinc, silver, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium and mixtures thereof. The molecular sieves of the CHA-type obtainable by the method can be used as SCR-catalytically active substances for the removal of nitrogen oxides from exhaust gases of combustion engines.
专利号:US-12331007-B2 优先权日:2021-10-15 标题 :Use of a multidentate phosphite ligand in the catalytic synthesis of adiponitrile 发明人:CHEN ZHIRONG; WU WENBIN; YIN HONG; ZHA ZENGSHI; WANG KEYAN; MA LI; HUANG GUODONG; ZHOU GUIYANG; XU YONG 权利人:ZHEJIANG NHU CO LTD; ZHEJIANG NHU SPECIAL MAT CO LTD; ZHEJIANG NHU NYLON MAT CO LTD 摘要:A multidentate phosphite ligand is used in the catalytic synthesis of adiponitrile. The ligand is represented by the following general formula (I). The method of catalytic synthesis of adiponitrile comprises primary hydrocyanation, isomerization, and secondary hydrocyanation reactions, wherein the catalyst adopted each comprises a phosphite ligand-nickel complex composed of a nickel precursor and a multidentate phosphite ligand. The ligand molecule has a higher electron cloud density, and the phosphorus content capable of participating in coordination in the ligand molecule per unit mass is higher, so that the catalytic activity of the catalyst is improved, and the amount of the catalyst is reduced.
专利号:US-9050776-B2 优先权日:2012-06-28 标 题 :Method of synthesis of high dispersed spherical Y or Nb doped lithium titanate oxide using titanium tetrachloride and lithium hydroxide 发明人:CHOI BYUNG HYUN; JI MI JUNG; KIM EUN KYUNG; KWON YOUNG JIN; JUNG SUNG HUN; AN YONG TAE 权利人:CHOI BYUNG HYUN; JI MI JUNG; KIM EUN KYUNG; KWON YOUNG JIN; JUNG SUNG HUN; AN YONG TAE; KOREA INST CERAMIC ENG & TECH 摘要:The present disclosure relates to a method of synthesis of Lithium Titanate Oxide used for a cathode of Lithium ion battery, the method comprising: (A) diluting TiCl 4 with TiOCl 2 ; (B) adding YCl 3 or NbCl 5 at the rate of 0.1Ëœ2 mol % to Ti(mol); (C) forming a complex salt by dissolving to put at least one selected from a group consisting of Hydroxy propyl cellulose or Polyethylene glycol in a solvent, the Hydroxy propyl cellulose being a complexing agent and being a dispersing agent as well, whereas the Polyethylene glycol being a dispersing agent; (D) synthesizing a titanium precursor by adding an aqueous ammonia solution; (E) preparing Y or Nb doped titanium dioxide(TiO 2 ) powder by heat-treating the synthetic product in a temperature of 500Ëœ700° C.; and (F) mixing the Y or Nb doped TiO 2 powder with LiOH.H 2 O and heat-treating the mixture in a temperature of 800Ëœ900° C.
专利号:US-11713329-B2 优先权日:2018-12-10 标 题 :Intermediates useful in the preparation of halichondrin compounds and methods for preparing the same 发明人:XU WEIPING 权利人:BEIJING TIENYI LUFU PHARMATECH CO LTD 摘要:The invention relates to intermediates useful in the preparation of halichondrin compounds, methods for preparing the same and use thereof, such as halichondrins, eribulin, or their analogs. The intermediates, the methods and use thereof are used for the synthesis of the C20-C26 fragment of halichondrin compounds. The raw materials in the synthetic route of the invention are cheap and easily obtained, the sources and the qualities of the raw materials are reliable. The choice of the methods useful in the synthesis of chiral central structures are based on the structural characteristics of the reactants, thus effectively improving the synthesis efficiency, reducing the difficulties and risks of product quality control, and avoiding the use of highly toxic and expensive organotin catalysts to significantly decrease costs and improve environmental friendliness.
专利号:US-5262373-A 优先权日:1990-04-20 标题:Process for the synthesis of metal oxides of high specific surface area and high porosity, oxides obtained and catalysts containing the said oxides 发明人:DURAND BERNARD; DE MAREUIL DOMINIQUE; VRINAT MICHEL; THIERRY DES GOURIERES 权利人:ELF AQUITAINE 摘要:PCT No. PCT/FR91/00322 Sec. 371 Date Jan. 17, 1992 Sec. 102(e) Date Jan. 17, 1992 PCT Filed Apr. 18, 1991 PCT Pub. No. WO91/16265 PCT Pub. Date Oct. 31, 1991.A process is provided for the synthesis for metal oxides of high specific surface area and high porosity which are particularly useful as catalyst supports. The process comprises forming a mixture of a salt of at least one metal and a molten salt medium comprising at least one alkali metal salt having an oxidizing effect, maintaining this mixture at the reaction temperature for the time necessary to convert the salt to oxide and thereafter isolating the metal oxide formed.
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合成参考文献
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