CAS: 529-23-7; 2-Aminobenzaldehyde

上下游产品

CAS号552-89-6 邻硝基苯甲醛 | CAS号5344-90-1 2-氨基苯甲醇 | CAS号5339-85-5 2-氨基苯乙醇 | CAS号16714-25-3 2-Azidobenzaldehyde | CAS号7439-89-6 铁粉 | CAS号31680-08-7 3-硝基-4-甲氧基苯甲醛 | CAS号109-83-1 2-甲胺乙醇 | CAS号459-57-4 对氟苯甲醛 | CAS号108-94-1 环己酮 | CAS号36192-63-9 2-氨基-4‘-甲基苯甲酮 | CAS号31407-25-7 2-氨基喹啉-3-甲腈 | CAS号31407-29-1 2-氨基喹啉-3-羧酸 | CAS号26709-65-9 2,3-dihydropyrr... | CAS号31739-56-7 2-(1H-吡咯)苯甲醛 | CAS号32413-08-4 2,3-喹啉二甲酸二乙酯 | CAS号50910-55-9 2-氨基-3,5-二溴苯甲醛 | CAS号4408-47-3 N,N'-双(2-氨基苯亚甲基)乙二胺 | CAS号3867-18-3 2-乙烯基苯胺 | CAS号33021-53-3 3-乙酰基喹啉

苯甲醯亞胺酸置于氢碘酸,碘,Copper(II) Bis(Trifluoromethanesulfonate)体系中,用 二甲基亚砜 作为反应溶剂,化学反应 2.0H,以30%的收率获得产物2-氨基苯甲醛
参考文献:铜催化的蒽酮与甲基酮的反应:蒽的位点选择性c5-二羰基化
标题:铜催化的蒽酮与甲基酮的反应:蒽的位点选择性c5-二羰基化
摘要:已经开发了一种铜催化的蒽的位点c5-二羰基化反应,用于使用甲基酮作为市售的羰基化试剂来合成1,2-二羰基化合物.该过程代表了第一个实现蒽的c5-二羰基化的例子,该过程涉及氧化的c Sp 3-H / C Sp 2-H交叉偶联反应以及热解性n-O键的裂解.
DOI:10.1002/adsc.202001334

专利信息

专利号:US-2023278959-A1
优先权日:2020-05-04
标题:Synthesis of Optically Active Indoline Derivatives Via Ruthenium(II)-Catalyzed Enantioselective C-H Functionalization
发明人：CUI XIN; LI ZHONG-YUAN; CHAMINDA LAKMAL HETTI HANDI
权利人:UNIV MISSISSIPPI STATE
摘要:Provided herein are a method of Ru(II)-catalyzed enantioselective synthesis of a cyclic compound and cyclic compounds formed therefrom. The method includes providing a precursor compound having an unfunctionalized C—H bond and activating the unfunctionalized C—H bond by reacting the precursor compound in the presence of co-catalysts including a Ru(II) arene complex and a chiral transient directing group (CTDG).

专利号:US-6133409-A
优先权日:1996-12-19
标 题:Process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and αβ-unsaturated carboxylic acid and aldehyde compounds
发明人：SALVINO JOSEPH M; MORTON GEORGE C; MASON HELEN J; LABAUDINIERE RICHARD F
权利人:AVENTIS PHARM PROD INC
摘要:This invention is directed to a process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and alpha , beta -unsaturated carboxylic acid and aldehyde compounds and to polymeric hydroxylamine resin compounds useful therefor.

专利号:EP-0946478-B1
优先权日:1996-12-19
标题 :Process for the solid phase synthesis of aldehydes, ketones and hydroxamic acid compounds
发明人：SALVINO JOSEPH M; MORTON GEORGE C; MASON HELEN J; LABAUDINIERE RICHARD F
权利人:AVENTIS PHARMA INC
摘要:This invention is directed to processes for the solid-phase synthesis of aldehydes, ketones, oximes, amines and hydroxamic acid compounds and to polymeric hydroxylamine resin compounds useful therefor.

专利号:US-6710208-B2
优先权日:1996-12-19
标题 :Process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and α,β-unsaturated carboxylic acid and aldehyde compounds
发明人：SALVINO JOSEPH M; MORTON GEORGE C; MASON HELEN J; LABAUDINIERE RICHARD F
权利人:AVENTIS PHARMA INC
摘要:This invention is directed to a process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and α,β-unsaturated carboxylic acid and aldehyde compounds and to polymeric hydroxylamine resin compounds useful therefor.

专利号:US-5280093-A
优先权日:1989-06-29
标题 :Chiral polymers for the synthesis of pure enantiomers of amino acids
发明人：JACQUIER ROBERT; CALMES MONIQUE; DAUNIS JACQUES
权利人:RHONE POULENC CHIMIE
摘要:The present invention relates to chiral polymers and to their uses for operations of asymmetric synthesis, deracemization and optical inversion. n These polymers are characterized in that they comprise: n a chiral unit n a functionalizing unit n an optional crosslinking unit n Application to chiral organic synthesis.

专利号:WO-2023284262-A1
优先权日:2021-07-13
标 题 :3,4-fused seven-membered heterocyclic oxindole, synthesis method therefor and application thereof
发明人：Li shuai-shuai; HU FANGZHI; Ding Zhanshuai; LI XINYAO
权利人:UNIV QINGDAO AGRICULTURAL
摘要:Disclosed is a 3,4-fused seven-membered heterocyclic oxindole, a synthesis method therefor and an application thereof. A structure of a 3,4-fused seven-membered nitrogen heterocyclic oxindole is provided in the present invention. A method for synthesizing same is also provided, comprising the following steps: reacting propargyl alcohol containing an isatin framework with a nucleophile under specific conditions to prepare a 3,4-fused seven-membered nitrogen heterocyclic oxindole. A pharmaceutical composition is provided in the present invention. Also provided in the present invention is an application of a 3,4-fused seven-membered nitrogen heterocyclic oxindole in the preparation of a drug for treating cancer. Provided in the present invention is a method for efficiently synthesizing 3,4-fused seven-membered nitrogen heterocyclic oxindoles having different structures. This is the first time achieving efficient synthesis of bioactive molecules containing both benzazepine and 3,4-fused heterooxidized oxindole structures on the basis of a hydrogen migration strategy.