CAS: 10500-57-9; 5,6,7,8-Tetrahydroquinoline

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CAS号1227460-08-3 (6-benzyl-6,7-d... | CAS号91-22-5 喹啉 | CAS号2568-20-9 3-(2-ox°Cyclohe... | CAS号148-24-3 8-羟基喹啉 | CAS号578-67-6 5-羟基喹啉 | CAS号635-46-1 1,2,3,4-四氢喹啉 | CAS号767-92-0 反-十氢喹啉 | CAS号10343-99-4 cis-decahydroqu... | CAS号5263-87-6 6-甲氧基喹啉 | CAS号100445-44-1 methyl 5,6,7,8-... | CAS号106057-23-2 8-氯-5,6,7,8-四氢喹啉 | CAS号14631-47-1 5,6,7,8-TETRAHY... | CAS号14631-48-2 5,6,7,8-四氢-1-喹啉 | CAS号91-22-5 喹啉 | CAS号635-46-1 1,2,3,4-四氢喹啉 | CAS号767-92-0 反-十氢喹啉 | CAS号84957-30-2 硫酸头孢喹肟 | CAS号56826-69-8 6,7-二氢-5H-喹啉-8-酮 | CAS号14631-46-0 5,6,7,8-四氢-8-羟基喹啉

喹啉置于氢气体系中,用 正庚烷 用作溶剂,100.0 °C,4.0 Mpa 条件下,反应 2.0H,反应生成5,6,7,8-四氢喹啉
参考文献:N官能化介孔二氧化硅上负载的rhnp:对催化剂稳定性和催化活性的影响
标题:N官能化介孔二氧化硅上负载的rhnp:对催化剂稳定性和催化活性的影响
摘要:研究了接枝在有序介孔二氧化硅(oms)上的胺和烟酰胺基团作为rhnps的稳定剂,Rhnps在几种底物的加氢反应中用作催化剂,包括羰基和芳基.通过在二氢压力下铑的有机金属前体的受控分解来制备功能化oms上负载的rhnp.通过光谱和物理技术(ftir,Tga,Bet,Sem,Tem,Edx,Xps)对所得材料进行了充分表征,以确认形成了二氧化硅表面负载的窄尺寸球形铑纳米粒子.使用烟酰胺官能化的oms作为载体可得到小的rhnp(2.3+/-0.3 Nm),并且在催化的苯乙酮氢化后,它们的大小和形状得以保持.相比之下,胺官能化的oms在催化反应后形成rhnp聚集体.负载的rhnps可以选择性地还原烯基,羰基,芳基和杂芳基,并且在苯酚和吗啉的还原胺化中具有活性,使用低浓度的贵金属(0.07-0.18 Mol%).
Doi:10.1039/d0Dt04213G

专利信息

专利号:US-7452994-B2
优先权日:2001-09-12
标 题 :Synthesis of enantiomerically pure amino-substituted fused bicyclic rings
发明人：MCEACHERN ERNEST J; BRIDGER GARY J; SKUPINSKA KRYSTYNA A; SKERLJ RENATO T; YANG WEN
权利人:ANORMED INC
摘要:This invention describes various processes for synthesis and resolution of racemic amino-substituted fused bicyclic ring systems. One process utilizes selective hydrogenation of an amino-substituted fused bicyclic aromatic ring system. An alternative process prepares the racemic amino-substituted fused bicyclic ring system via nitrosation. In addition, the present invention describes the enzymatic resolution of a racemic mixture to produce the (R)- and (S)-forms of amino-substituted fused bicyclic rings as well as a racemization process to recycle the unpreferred enantioner. Further provided by this invention is an asymmetric synthesis of the (R)- or (S)-enantiomer of primary amino-substituted fused bicyclic ring systems.

专利号:US-7138526-B1
优先权日:1999-06-15
标 题 :Solid phase synthesis of n,n-disubstituted diazacycloalkylcarboxy derivatives
发明人：HERPIN TIMOTHY F; MORTON GEORGE C; SALVINO JOSEPH M
权利人:AVENTIS PHARMA INC
摘要:A method for the solid phase synthesis of N,N-disubstituted diazacycloalkylcarboxy derivatives of general formula (I) and (II) is claimed. Examples include piperazine-2-carboxamide. The method is applicable to the synthesis or large combinatorial libraries

专利号:US-6127515-A
优先权日:1997-11-18
标 题:Functionalized resin for the synthesis of amides and peptides
发明人：MANFRE FRANCO; VANASSE BENOIT J; LABAUDINIERE RICHARD F; MORTON GEORGE C
权利人:AVENTIS PHARM PROD INC
摘要:This invention is directed to a functionalized amino resin of formula ##STR1## wherein S is a solid support; R is H or alkyl; A is ##STR2## Y is OH or OCOR 1 ; and R 1 is aliphatic or aromatic which is useful for the solid phase synthesis of amides, peptides and hydroxamic acids.

专利号:US-6133409-A
优先权日:1996-12-19
标 题:Process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and αβ-unsaturated carboxylic acid and aldehyde compounds
发明人：SALVINO JOSEPH M; MORTON GEORGE C; MASON HELEN J; LABAUDINIERE RICHARD F
权利人:AVENTIS PHARM PROD INC
摘要:This invention is directed to a process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and alpha , beta -unsaturated carboxylic acid and aldehyde compounds and to polymeric hydroxylamine resin compounds useful therefor.

专利号:US-2023212204-A1
优先权日:2020-01-16
标题:Reagents and their use for modular enantiodivergent synthesis of c-p bonds
发明人：XU DONGMIN; RIVAS-BASCÓN NAZARET; KNOUSE KYLE W; PADIAL NATALIA; ZHENG BIN; VANTOUROUT JULIEN; SCHMIDT MICHAEL; EASTGATE MARTIN D; BARAN PHI
权利人:BRISTOL MYERS SQUIBB CO; SCRIPPS RESEARCH INST
摘要:The disclosure describes chiral P(V)-based reagents and their uses for the modular, scalable, and stereospecific synthesis of chiral phosphines, phosphine oxides and particular oligonucleotides.

专利号:US-6710208-B2
优先权日:1996-12-19
标题 :Process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and α,β-unsaturated carboxylic acid and aldehyde compounds
发明人：SALVINO JOSEPH M; MORTON GEORGE C; MASON HELEN J; LABAUDINIERE RICHARD F
权利人:AVENTIS PHARMA INC
摘要:This invention is directed to a process for the solid phase synthesis of aldehyde, ketone, oxime, amine, hydroxamic acid and α,β-unsaturated carboxylic acid and aldehyde compounds and to polymeric hydroxylamine resin compounds useful therefor.