物理性质
- 熔点-91 °C
- 沸点107.8±3.0 °C at 760 mmHg
- 闪点13.9±0.0 °C
- 密度0.9±0.1 g/cm3
- PSA:26.3
- LogP:1.36
- 折射率1.389
- 蒸汽压26.6±0.2 mmHg at 25°C
- 溶解性Slightly soluble in water, miscible with alcohol and oils.
- 敏感性1.干燥时对金属无腐蚀性,有水分存在时,水解生成腐蚀性很强的甲酸。贮存时应经常检查其酸度。无甲酸存在时可用软钢或铝制容器贮存,但不宜使用铜制容器。甲酸丁酯有麻醉作用,且刺激性强。容易水解生成甲酸和丁醇。2.稳定性 稳定3.禁配物 强氧化剂、强酸、强碱4.聚合危害 不聚合
- 外观形态无色液体,具有果子香味。
- 储存条件储存注意事项储存于阴凉、通风的库房。远离火种、热源。库温不宜超过37°C。保持容器密封保存。应与氧化剂、酸类、碱类分开存放,切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备和合适的收容材料。
- 产品应用用作溶剂,用于香料制造,有机合成,化学试剂等.
- 性质描述无色液体,有水果香味.熔点-95.8°C,沸点98.4°C,相对密度0.8854(20/4°C),折射率1.3857,闪点180°C,蒸气压3.73kPa(25°C),汽化热363J/g,比热容61.2J/(g·°C).微溶于水,溶于丙酮,能与乙醇乙醚等有机溶剂混溶.能很好地溶解硝基纤维素,醋酸纤维素以及纤维素醚等.
MSDS等安全信息
- GHS象形图


- GHS符号GHS02 & GHS07;
注释: Flame & Exclamation mark - 危险类别易燃液体 类别2
特定目标器官毒性 - 单次接触 类别3
严重眼刺激 类别2
STOT SE 2 - 警示词Danger(危险)
- 危险描述H225 |高度易燃液体和蒸气.
H335 |可能引起呼吸道刺激.
H319 |造成严重眼刺激.
H371 |可能损害器官. - 防范说明P210, P233, P240, P241, P242, P243, P261, P264+P265, P271, P280, P303+P361+P353, P304+P340, P305+P351+P338, P319, P337+P317, P370+P378, P403+P233, P403+P235, P405, and P501
- UN编号1128.0
- 危险品标志F,Xi
- 安全声明S9-S16-S24-S33
- 危险类别码R36/37,R11
- WGK Germany1
欧盟法规
统一分类与标签压力设备指令-第1组危险流体ECHA物质欧盟气雾剂指令-标签制度工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单上下游产品
CAS号109-69-3 1-氯丁烷 | CAS号124-38-9 二氧化碳 | CAS号64-18-6 甲酸 | CAS号71-36-3 正丁醇 | CAS号1623-88-7 5-氯甲基呋喃-2-甲醛 | CAS号109-94-4 甲酸乙酯 | CAS号106-98-9 正丁烯 | CAS号123-76-2 乙酰丙酸 | CAS号72773-04-7 1H-苯并三唑-1-甲醛 | CAS号67-47-0 5-羟甲基糠醛 | CAS号10580-24-2 Undecanoic acid... | CAS号91526-41-9 Decanoic acid, ... | CAS号105-76-0 马来酸二丁酯 | CAS号925-21-3 马来酸单丁酯 | CAS号4343-75-3 4-氨基-3-巯基-4H-1,... | CAS号1825-65-6 BUTOXYTRIMETHYL... | CAS号128728-88-1 1-formyloxy-2-t... | CAS号630-19-3 三甲基乙醛 | CAS号23731-39-7 甲酸甲酯-D3 | CAS号3007-95-2 1-Naphthaleneca...正戊醛置于葡萄糖,Glucose Dehydrogenase From B. Megaterium,Nicotinamide Adenine Dinucleotide Phosphate,Baeyer-villiger Monooxygenase Afl838 From Aspergillus Flavus体系中,用 甲醇 作为反应溶剂,化学反应生成 甲酸丁酯
参考文献:真菌baeyer-Villiger单加氧酶合成烷基甲酸酯
标题:真菌baeyer-Villiger单加氧酶合成烷基甲酸酯
摘要:选择方面:甲酸烷基酯的合成采用baeyer-Villiger单加氧酶进行.烷基甲酸酯对相应的伯醇产物的区域选择性和自水解的速率受底物浓度影响.
DOI:10.1002/cbic.201600684
海关参考信息
- 2905121000-正丙醇
2905130000-正丁醇
2912110000-甲醛
2915110000-甲酸 - 💡 提示:海关信息按照顺序优先匹配,如需确认的海关信息,请参考相关资料。
- 详情请参考:📖 海关编码查询和海关进出口税则
专利信息
专利号:US-9353057-B2
优先权日:2003-12-30
标 题:Synthesis of acyloxyalkyl carbamate prodrugs and intermediates thereof
发明人:GALLOP MARK A; DAI XUEDONG; SCHEUERMAN RANDALL A; RAILLARD STEPHEN P; MANTHATI SURESH K; YAO FENMEI; PHAN THU; LUDWIKOW MARIA; PENG GE; BHAT SEEMA
权利人:XENOPORT INC
摘要:Methods for synthesis of 1-(acyloxy)-alkyl carbamates, particularly, the synthesis of 1-(acyloxy)-alkyl carbamate prodrugs of primary or secondary amine-containing drugs are described. Also described are methods for synthesis of 1-(acyloxy)-alkyl N-hydroxysuccinimidyl carbonates which are useful intermediates in the synthesis of 1-(acyloxy)-alkyl carbamates are also described.
专利号:WO-9312076-A1
优先权日:1991-12-13
标题:Reagents for automated synthesis of peptide analogs
发明人:WEBB THOMAS ROY
权利人:CORVAS INT INC
摘要:Reagents suitable for synthesis of peptide analogs using automated peptide synthesis and procedures for synthesis of peptide analogs are provided.
专利号:US-9126995-B2
优先权日:2011-11-08
标题:Method for catalytic asymmetric synthesis of optically active isoxazoline compound and optically active isoxazoline compound
发明人:TOYAMA KEN-ICHI; MORIYAMA YUJI; MATOBA KAZUTAKA; YAOSAKA MANABU; IKEDA EITATSU
权利人:NISSAN CHEMICAL IND LTD
摘要:There is provided a method for catalytic asymmetric synthesis of optically active isoxazoline compound and an optically active isoxazoline compound. A method for catalytic asymmetric synthesis of optically active isoxazoline compound of a formula (6) including reacting an α,β-unsaturated carbonyl compound of a formula (1) and a hydroxylamine in a solvent in the presence of a base by adding a chiral phase transfer catalyst. An optically active isoxazoline compound of a formula (13) that can be synthesized by the method.
专利号:US-10253153-B2
优先权日:2015-04-24
标题 :Linker and support for solid phase synthesis of nucleic acid, and production method of nucleic acid using said support
发明人:MAETA ERI; MORI KENJIRO; HORIE SHOHEI; ITO TAKAHIKO; SAITO SHOICHIRO; NAGAO RYUHEI
权利人:NITTO DENKO CORP
摘要:The present invention provides a linker for solid phase synthesis of nucleic acid, which consists of a compound represented by the formula (I) or the formula (II), a support for solid phase synthesis of nucleic acid, which has a structure represented by the formula (III), and a production method of a nucleic acid, which uses the support: n nwherein each symbol is as defined in the SPECIFICATION.
专利号:US-2006128930-A1
优先权日:2004-12-03
标题 :Synthesis of sterically hindered phenol based macromolecular antioxidants
发明人:DHAWAN ASHISH; CHOLLI ASHOK L
权利人:DHAWAN ASHISH; CHOLLI ASHOK L
摘要:Disclosed is a method for the synthesis of sterically hindered polymeric antioxidants based on phenol type antioxidant monomers. The method includes polymerizing and alkylating a phenol containing monomer represented by the following structural formula: n n nto produce a sterically hindered polymeric macromolecular antioxidant. X, R 10 and q are as defined herein. The disclosed method is a simple, direct and economical process for the synthesis of sterically hindered polymeric macromolecular antioxidants.
专利号:US-9139515-B2
优先权日:2011-08-19
标 题:Synthesis of R-biphenylalaninol
发明人:HERMSEN PETRUS JOHANNES; ERMANN PETER HANS; RIEBEL PETER HANS; WOLBERG MICHAEL; DE VRIES ANDREAS HENDRIKUS MARIA
权利人:HERMSEN PETRUS JOHANNES; ERMANN PETER HANS; RIEBEL PETER HANS; WOLBERG MICHAEL; DE VRIES ANDREAS HENDRIKUS MARIA; DPX HOLDINGS BV
摘要:This invention relates to a novel process for the synthesis of R-biphenylalaninol and to intermediate compounds that are formed in the process according to the invention, i.e. novel intermediates useful in the synthesis of R-biphenylalaninol. The invention also relates to R-biphenylalaninol, The process according to the invention, the intermediates to of R-biphenylalaninol and of R-biphenylalaninol are all useful in the synthesis of pharmaceutically active compounds.