专利号:US-11718536-B2 优先权日:2020-07-29 标题 :Solvent-free synthesis of lanthanide oxide and mixed lanthanide oxide nanoparticles 发明人:Treadwell LaRico Juan; BREGMAN AVI GABRIEL; RINGGOLD MARISSA 权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC 摘要:Lanthanide oxides and mixed lanthanide oxides can be produced using furnace or microwave assisted solid-state synthesis. The use of Ln-tri(methylsilyl)amide-based precursors yields spherical nanoparticles. The formation of spherical shaped nanoparticles is likely due to the preferential single-step decomposition of the Ln-TMS as well as the low activation energy to overcome decomposition. Reaction temperature, initial metal ion ratio, and reaction dwell time can be used to control the final nanoparticle size. The method enables solvent-free, high-yield synthesis of morphology-controlled lanthanide oxides.
专利号:WO-2024123268-A1 优先权日:2022-12-09 标 题 :Production of silver nanoparticles by green synthesis using hazelnut husk extract 发明人:AKDOGAN OZAN; GUNDUZ AKDOGAN NILAY; SIVRI DAMLA; KUREL ALI 权利人:BAHCESEHIR UNIV; PIRI REIS UNIV 摘要:The invention relates to synthesis of nanoparticles from hazelnut husk extract by green synthesis with high efficiency. Use of chemical is limited in the present invention and therefore the synthesis of nanoparticles is provided by green chemistry in the present invention. Said hazelnut may be Corylus and said hazelnut husk may be cob or shell of the hazelnut. In an embodiment of the invention said Corylus may be Colyrus colurna, Corylus americana Corylus avellana, Corylus avellana var. Avellana, Corylus avellana var. Pontica, Corylus chinensis, Corylus colchica, Corylus × colurnoides, Corylus cornuta, Corylus cornuta ssp. californica, Corylus cornuta ssp. cornuta, Corylus fargesii, Corylus ferox, Corylus ferox var. ferox, Corylus ferox var. thibetica, Corylus heterophylla, Corylus heterophylla var. heterophylla, Corylus heterophylla var. sutchuensis, Corylus jacquemontii, Corylus maxima, Corylus potaninii, Corylus sieboldiana, Corylus sieboldiana var. mandshurica, Corylus sieboldiana var. sieboldiana, Corylus wangii, Corylus wulingensis or Corylus yunnanensis.
专利号:US-8623927-B2 优先权日:2008-07-24 标题:Catalyst for synthesizing methanol from synthesis gas and preparation method thereof 发明人:KANG SUK-HWAN; BAE JONG WOOK; JUN KI WON; MIN KEH-SIK; SONG SEOK-LYONG; JEONG SAM-HEON 权利人:KANG SUK-HWAN; BAE JONG WOOK; JUN KI WON; MIN KEH-SIK; SONG SEOK-LYONG; JEONG SAM-HEON; HYUN DAI HEAVY IND CO LTD; KOREA RES INST CHEM TECH 摘要:Disclosed are a catalyst for synthesis of methanol from synthesis gas and a method for preparing the same. The catalyst includes a Cu—Zn—Al oxide containing CuO, ZnO and Al 2 O 3 in a predetermined ratio or Cu—Zn—Al—Zr oxide containing CuO, ZnO, Al 2 O 3 and ZrO 2 in a predetermined ratio, in combination with a cerium-zirconium oxide obtained by a sol-gel process. As compared to the existing Cu—Zn—Al catalysts for synthesizing methanol, the catalyst disclosed herein inhibits formation of byproducts and improves yield of methanol. Therefore, it is possible to improve methanol purification efficiency and carbon conversion efficiency.
专利号:US-2023226527-A1 优先权日:2020-11-03 标 题 :Synthesis of high surface area, high entropy oxides 发明人:CHOU STANLEY SHIHYAO; RILEY CHRISTOPHER RYAN; DATYE ABHAYA; DE LA RIVA ANDREW 权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC; UNM RAINFOREST INNOVATIONS 摘要:High surface area, high entropy oxides comprising multiple metal cations in a single-phase fluorite lattice material enables intrinsic catalytic activity without platinum group metals, tunable oxygen storage capacity, and thermal stability. These properties can be obtained through a facile sol-gel synthesis to provide a low-temperature route for production of phase-pure multi-cationic oxides. The resulting materials achieved significantly higher surface area and catalytic performance, taking advantage of all the properties endowed by the various cations in the composition.
专利号:US-2024327997-A1 优先权日:2023-03-28 标题 :Electrocatalytic Conversion of Nitrates and Nitrites to Ammonia 发明人:ATANASSOV PLAMEN; MURPHY EAMONN; LIU YUANCHAO; SPOERKE ERIK DAVID 权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC; UNIV CALIFORNIA 摘要:Electrocatalytic reduction of waste nitrates (NO3−) enables the synthesis of ammonia (NH3) in a carbon neutral and decentralized manner. The present invention uses atomically dispersed transition metal-nitrogen-carbon (M-N—C) catalysts with varying metal centers to uniquely favor mono-nitrogen products (e.g., NH3) via the electrochemical nitrate reduction reaction (NO3RR).
专利号:US-8759247-B2 优先权日:2011-12-27 标 题 :Methanol electro-oxidation catalyst and method of making the same 发明人:ZAIDI SYED MOHAMMED JAVAID; RAHMAN SALEEM UR; AHMED SHAKEEL; BELLO MUKHTAR 权利人:ZAIDI SYED MOHAMMED JAVAID; RAHMAN SALEEM UR; AHMED SHAKEEL; BELLO MUKHTAR; UNIV KING FAHD PET & MINERALS 摘要:The methanol electro-oxidation catalysts include nano-oxides of rare earth metals (i.e., cesium, praseodymium, neodymium and samarium) and platinum nano-particles. The nano-oxides of the rare earth metals are dispersed during synthesis of a support material, preferably formed from mesoporous carbon. The platinum nano-particles form between about 10 wt % and about 15 wt % of the methanol electro-oxidation catalyst, the rare earth metal forms between about 10 wt % and about 15 wt % of the methanol electro-oxidation catalyst, and carbon and oxygen forming the balance (between about 70 wt % and about 80 wt %) of the methanol electro-oxidation catalyst.
参考文献:10.1007/s11356-019-05601-4 摘要:Zhao X, Wu W, Yan Y. Efficient abatement of an iodinated X-ray contrast media iohexol by Co(II) or Cu(II) activated sulfite autoxidation process. Environmental Science and Pollution Research. 2019 Jun 25;26(24):24707–19. doi: 10.1007/s11356-019-05601-4. 参考文献:10.1007/s11356-021-17669-y 摘要:Wang Y, Xia X, Gao S, Zhao X, Wang G, Han X. Synthesis of Ag/BiOBr/CeO2 composites with enhanced photocatalytic degradation for sulfisoxazole. Environmental Science and Pollution Research. 2022 Feb 15;29(30):46200–13. doi: 10.1007/s11356-021-17669-y.