苯磺酸置于对甲苯磺酸体系中,化学反应生成2,4-二甲基苯酚 参考文献:Method Of Purifying 2,4-Xylenol 标题:Method Of Purifying 2,4-Xylenol 摘要:从含有2,5-二甲基苯酚的原始2,4-二甲基苯酚异构物混合物中,可以通过在芳香磺酸的存在下选择性地将2,5-二甲基苯酚与醛反应,从而将2,5-二甲基苯酚转化为二甲基苯酚-醛缩合物,随后通过蒸馏等方法分离2,4-二甲基苯酚,从而高产高纯度地获得2,4-二甲基苯酚.
专利号:WO-2009018504-A1 优先权日:2007-08-01 标题 :Process for the synthesis of diaminopyridine and related compounds 发明人:RITTER JOACHIM C 权利人:DU PONT; RITTER JOACHIM C 摘要:A process is provided for the synthesis of a diaminopyridine, such as 2,6-diaminopyridine and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a chlorine-ammonia displacement in the presence of a copper source.
专利号:US-8084569-B2 优先权日:2006-12-21 标 题 :Process for the synthesis of diaminopyridines from glutarimidines 发明人:MINTER AARON; STOKES BERLIN 权利人:MINTER AARON; STOKES BERLIN; DU PONT 摘要:A liquid-phase process is provided for the synthesis from glutarimidines of diaminopyridines and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:US-8022167-B2 优先权日:2006-12-21 标 题 :Process for the synthesis of diaminopyridines from glutaronitriles 发明人:MINTER AARON; STOKES BERLIN 权利人:MINTER AARON; STOKES BERLIN 摘要:A liquid-phase process is provided for the manufacture from glutaronitriles and related compounds of 2,6-diaminopyridine and related compounds, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:US-7999057-B2 优先权日:2008-07-08 标 题:Gas-phase process for the synthesis of diaminopyridines from glutaronitriles 发明人:HUTCHENSON KEITH W; MINTER AARON; SUNSHINE GREGG 权利人:DU PONT 摘要:A gas-phase, continuous process is provided for the manufacture of 2,6-diaminopyridine and related compounds from glutaronitriles, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:US-2011301314-A1 优先权日:2008-12-18 标题:Continuous liquid-phase process for the synthesis of diaminopyridines from glutaronitriles 发明人:HUTCHENSON KEITH W; MINTER AARON 权利人:HUTCHENSON KEITH W; MINTER AARON; DU PONT 摘要:A liquid-phase, continuous process is provided for the manufacture of 2,6-diaminopyridine and related compounds from glutaronitriles, which are used industrially as compounds and as components in the synthesis of a variety of useful materials. The synthesis proceeds by means of a dehydrogenative aromatization process.
专利号:US-3772389-A 优先权日:1971-06-24 标 题:Process for the synthesis of phenyl esters 发明人:LOWRANCE W 权利人:EASTMAN KODAK CO 摘要:A PROCESS FOR THE SYNTHESIS OF PHENYL ESTERS DIRECTLY FROM THE CORRESPONDING PHENOLS AND CARBOXYLIC ACIDS WHICH COMPRISES CONTACTING A PHENOLIC COMPOUND HAVING AT LEAST ONE HYDROGEN ATOM ADJACENT THE ACTIVE HYDROXYL GROUP WITH A CARBOXYLIC ACID COMPOUND CONTAINING AT LEAST ONE ACTIVE CARBOXYLIC GROUP IN THE PRESENCE OF A CATALYTIC AMOUNT OF A BORATE-SULFURIC ACID CATALYST COMPLEX. THE PROCESS IS CARRIED OUT IN A SINGLE STAGE REACTOR WHICH MAY BE OPERATED AT FROM 75*C. TO 285*C. UNDER ATMOSPHERIC, SUBATMOSPHERIC OR SUPERATMOSPHERIC PRESSURE. IF DESIRABLE, A SOLVENT CAN BE EMPLOYED.
参考文献:10.1007/s00216-010-3496-z 摘要:Saraji M, Marzban M. Determination of 11 priority pollutant phenols in wastewater using dispersive liquid—liquid microextraction followed by high-performance liquid chromatography—diode-array detection. Analytical and Bioanalytical Chemistry. 2010 Feb 13;396(7):2685–93. doi: 10.1007/s00216-010-3496-z. 参考文献:10.1007/s00774-011-0291-7 摘要:Burt-Pichat B, Follet H, Toulemonde G, Arlot M, Delmas P, Chapurlat R. Methodological approach for the detection of both microdamage and fluorochrome labels in ewe bone and human trabecular bone. Journal of Bone and Mineral Metabolism. 2011 Jul 13;29(6):756–64. doi: 10.1007/s00774-011-0291-7. 参考文献:10.1111/j.1600-9657.2011.01040.x 摘要:Ferreira MM, Botelho MF, Carvalho L, Silva MR, Oliveiros B, Carrilho EV. Evaluation of dentin formed in autogenous tooth transplantation in the dog: a comparison between one- and two-stage surgical techniques. Dent Traumatol. 2012 Apr;28(2):97–100. doi: 10.1111/j.1600-9657.2011.01040.x. 参考文献:10.1111/j.1472-765x.2011.03123.x 摘要:Davis CK, Denman SE, Sly LI, McSweeney CS. Development of a colorimetric colony-screening assay for detection of defluorination by micro-organisms. Lett Appl Microbiol. 2011 Oct;53(4):417–23. doi: 10.1111/j.1472-765x.2011.03123.x. 参考文献:10.1155/2011/467305 摘要:Babich H, Schuck AG, Weisburg JH, Zuckerbraun HL. Research Strategies in the Study of the Pro-Oxidant Nature of Polyphenol Nutraceuticals. Journal of Toxicology. 2011;2011():1–12. doi: 10.1155/2011/467305.